CN: 6

fac–[Th{OSi(OBuᵗ₃)}₃(N₃)₃]²⊖

Formula Unicode styled: 
fac–[Th{OSi(OBuᵗ₃)}₃(N₃)₃]²⊖
Compound name(s): 
tris(tri-t-butoxysilanolato)-tris(azido)-thorium(2-)
Central atom: 
Thorium
Compound type: 
Molecular
Valence Number (VN): 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 18
CLOVEBXZ: 
Th«V4C6OIVE18B9Z0X6L3»2⊖
MLXZQ± class: 
[MX6L3]2-
MLXZ class: 
MX4L5
Attached groups: 
OSi(OBuᵗ)₃ (tri-t-butoxy-siloxy XL)
N₃ (azido)

catena–2D-[Hg(μ₂-Br)₂(μ₂-Bpy-4,4')]

Formula Unicode styled: 
catena–2D-[Hg(μ₂-Br)₂(μ₂-Bpy-4,4')]
Compound name(s): 
catena-(μ₂-4,4'-bipyridinium)-bis(μ₂-bromo)-mercury
Central atom: 
Mercury
Compound type: 
Catena-2D
Valence Number (VN): 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 12
CLOVEBXZ: 
Hg«V2C6OIIE12B6Z0X2L4»
MLXZQ± class: 
[MX2L4]
MLXZ class: 
MX2L4
Attached groups: 
Br (μ₂-bromo)
Bpy (μ₂-bipyridine-4,4')

catena–3D-[Hg{C(CN)₃-κN}₂]

Formula Unicode styled: 
catena–3D-[Hg{C(CN)₃-κN}₂]
Compound name(s): 
catena-(bis(μ₃-tricyanomethanide)-mercury
Central atom: 
Mercury
Compound type: 
Catena-3D
Valence Number (VN): 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 12
CLOVEBXZ: 
Hg«V2C6OIIE12B6Z0X2L4»
MLXZQ± class: 
[MX2L4]
MLXZ class: 
MX2L4
Attached groups: 
C(CN)₃ (tricyanomethyl-κN)

catena–1D-trans–[Hg(μ₂-Cl)([16]aneN₄-κ⁴N)]⊕

Formula Unicode styled: 
catena–1D-trans–[Hg(μ₂-Cl)([16]aneN₄-κ⁴N)]⊕
Compound name(s): 
catena-[(μ₂-chloro)-(1,5,9,13-tetra-azacyclohexadecane-N1,N5,N9,N13)-mercury(1+)]
Central atom: 
Mercury
Compound type: 
Catena-1D
Valence Number (VN): 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 12
CLOVEBXZ: 
Hg«V2C6OIIE12B6Z0X1L5»⊕
MLXZQ± class: 
[MX1L5]+
MLXZ class: 
MX2L4
Attached groups: 
Cl (μ₂-chloro)
[16]aneN₄ (1,5,9,13-tetraazacyclohexadodecane-κ⁴N)

cis–[Tb(OSiPh₃)₄(Thf)₂]

Formula Unicode styled: 
cis–[Tb(OSiPh₃)₄(Thf)₂]
Compound name(s): 
bis(tetrahydrofuran)-tetrakis(triphenylsilanolato)-terbium
Central atom: 
Terbium
Compound type: 
Molecular
Valence Number (VN): 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 11
CLOVEBXZ: 
Tb«V4C6OIVE11B6Z0X4L2»
MLXZQ± class: 
[MX4L2]
MLXZ class: 
MX4L2
Attached groups: 
OSiPh₃ (triphenylsiloxy)
Thf (tetrahydrofuran)

cis–[Ce(OSiPh₃)₄(Thf)₂]

Formula Unicode styled: 
cis–[Ce(OSiPh₃)₄(Thf)₂]
Compound name(s): 
bis(tetrahydrofuran)-tetrakis(triphenylsilanolato)-cerium
Central atom: 
Cerium
Compound type: 
Molecular
Valence Number (VN): 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 12
CLOVEBXZ: 
Ce«V4C6OIVE12B6Z0X4L2»
MLXZQ± class: 
[MX4L2]
MLXZ class: 
MX4L2
Attached groups: 
OSiPh₃ (triphenylsiloxy)
Thf (tetrahydrofuran)

trans–[Np(μ₂-OH)(O)₄]²⊖

Formula Unicode styled: 
trans–[Np(μ₂-OH)(O)₄]²⊖
Compound name(s): 
tetraoxo-hydroxo-neptunium(2-)
Central atom: 
Neptunium
Compound type: 
Molecular
Valence Number (VN): 
VN: 7
Oxidation Number (ON) (Roman numerals): 
ON: (VII)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 20
CLOVEBXZ: 
Np«V7C6OVIIE20B10Z0X9L1»2⊖
MLXZQ± class: 
[MX9L1]2-
MLXZ class: 
MX7L3
Attached groups: 
OH (μ₂-hydroxy)
O (oxo X₂)

fac–[Lu(NCS-κN)₃(OPPh₃)₃]

Formula Unicode styled: 
fac–[Lu(NCS-κN)₃(OPPh₃)₃]
Compound name(s): 
fac-tris(isothiocyanato)-tris(triphenylphosphine oxide)-lutetium
Central atom: 
Lutetium
Compound type: 
Molecular
Valence Number (VN): 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (III)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 12
CLOVEBXZ: 
Lu«V3C6OIIIE12B6Z0X3L3»
MLXZQ± class: 
[MX3L3]
MLXZ class: 
MX3L3
Attached groups: 
NCS (isothiocyanato-κN)
OPPh₃ (triphenylphosphane oxide)

cis–[W₂(Cl)₄(μ₂-Cl)₂(PhC≡CPh)₂(μ₂–O)]

Formula Unicode styled: 
cis–[W₂(Cl)₄(μ₂-Cl)₂(PhC≡CPh)₂(μ₂–O)]
Compound name(s): 
(μ₂-oxo)-bis((μ₂-chloro)-dichloro-(η²-diphenylacetylene)-tungsten)
Central atom: 
Tungsten
Compound type: 
Molecular
Valence Number (VN): 
VN: 4
Oxidation Number (ON) (Roman numerals): 
ON: (IV)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 14
CLOVEBXZ: 
W«V4C6OIVE14B6Z0X4L2»
MLXZQ± class: 
[MX4L2]
MLXZ class: 
MX4L2
Attached groups: 
Cl (chloro)
Cl (μ₂-chloro)
PhC≡CPh (diphenylethyne)
O (μ₂–oxo X+X)

cis,trans–[W₂(Cl)₄(Dme)₂(PhC≡CPh)₂(N₂)]

Formula Unicode styled: 
cis,trans–[W₂(Cl)₄(Dme)₂(PhC≡CPh)₂(N₂)]
Compound name(s): 
(μ₂-dinitrogen)-bis(dichloro-(1,2-dimethoxyethane-O,O')-(η²-diphenylacetylene)-tungsten)
Central atom: 
Tungsten
Compound type: 
Molecular
Valence Number (VN): 
VN: 2
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 16
CLOVEBXZ: 
W«V2C6OIIE16B6Z0X2L4»
MLXZQ± class: 
[MX2L4]
MLXZ class: 
MX2L4
Attached groups: 
Cl (chloro)
Dme (dimethoxyethane)
PhC≡CPh (diphenylethyne)
N₂ (dinitrogen)

trans–[Ir₂(Cl)₂(CO)₂(μ₂-Dmpm)₂(MeO₂C)C≡C(CO₂Me)]

Formula Unicode styled: 
trans–[Ir₂(Cl)₂(CO)₂(μ₂-Dmpm)₂(MeO₂C)C≡C(CO₂Me)]
Compound name(s): 
(μ₂-dimethyl-acetylenedicarboxylate)-bis(bis(diphenylphosphino)-methane-P,P')-dicarbonyl-dichloro-di-iridium(Ir—Ir)
Central atom: 
Iridium
Compound type: 
Molecular
Valence Number (VN): 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 18
CLOVEBXZ: 
Ir«V3C5.5OIIE18B6Z0X3L3»
MLXZQ± class: 
[MX3L3]
MLXZ class: 
MX3L3
Attached groups: 
Cl (chloro)
CO (carbonyl)
Dmpm (μ₂-1,2-bis-(dimethylphosphino)methane)
(MeO₂C)C≡C(CO₂Me) (dimethylacetylenedicarboxylate X₂)