Rhenium

trans–[Re(CO)₄(PMe₂Ph)]₂

Formula Unicode styled: 
trans–[Re(CO)₄(PMe₂Ph)]₂
Compound name(s): 
bis-[(Tetracarbonyl-dimethylphenylphosphine-rhenium(Re—Re)]
Central atom: 
Rhenium
Compound type: 
Oligomer
Valence Number (VN): 
VN: 1
Oxidation Number (ON) (Roman numerals): 
ON: (O)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 18
CLOVEBXZ: 
Re«V1C6OOE18B6Z0X1L5»
MLXZQ± class: 
[MX1L5]
MLXZ class: 
MX1L5
Attached groups: 
CO (carbonyl)
PMe₂Ph (dimethylphenylphosphane)

[Re(Xy)(⭀NBuᵗ)(O)(O)]₂

Formula Unicode styled: 
[Re(Xy)(⭀NBuᵗ)(O)(O)]₂
Compound name(s): 
bis-[(μ₂-oxo)-oxo-(t-Butylimido-N)-xylyl-rhenium]
Central atom: 
Rhenium
Compound type: 
Oligomer
Valence Number (VN): 
VN: 7
Oxidation Number (ON) (Roman numerals): 
ON: (VII)
Coordination Number (CN): 
CN: 4
Electron Number (EN): 
EN: 18
CLOVEBXZ: 
Re«V7C4OVIIE18B9Z0X7L2»
MLXZQ± class: 
[MX7L2]
MLXZ class: 
MX7L2
Attached groups: 
Xy (xylyl)
⭀NBuᵗ (⭀N t-butylimino)
O (oxo X₂)
O (oxo ⭀O X₂L)

[Re(μ₂-SPh)(S₂C₆H₄-κ²S)(O)]₂

Formula Unicode styled: 
[Re(μ₂-SPh)(S₂C₆H₄-κ²S)(O)]₂
Compound name(s): 
bis-[(μ₂-Phenylthiolato)-oxo-(1,2-benzenedithiolato)-rhenium
Central atom: 
Rhenium
Compound type: 
Oligomer
Valence Number (VN): 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN): 
CN: 5
Electron Number (EN): 
EN: 16
CLOVEBXZ: 
Re«V5C5OVE16B7Z0X5L2»
MLXZQ± class: 
[MX5L2]
MLXZ class: 
MX5L2
Attached groups: 
SPh (μ₂-phenylthio)
S₂C₆H₄-o (benzene-1,2-dithiolato-κ²S)
O (oxo ⭀O X₂L)

[Re(SnPh₂)(CO)₄]₂

Formula Unicode styled: 
[Re(SnPh₂)(CO)₄]₂
Compound name(s): 
bis-[(μ₂-Diphenylstannyl)-tetracarbonyl-rhenium(Re—Re)]
Central atom: 
Rhenium
Compound type: 
Oligomer
Valence Number (VN): 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN): 
CN: 7
Electron Number (EN): 
EN: 18
CLOVEBXZ: 
Re«V3C7OIIE18B7Z0X3L4»
MLXZQ± class: 
[MX3L4]
MLXZ class: 
MX3L4
Attached groups: 
SnPh₂ (diphenylstannene)
CO (carbonyl)

[Re(SiPh₂)(CO)₄]₂

Formula Unicode styled: 
[Re(SiPh₂)(CO)₄]₂
Compound name(s): 
bis-[(μ₂-Diphenylsilylene)-tetracarbonyl-rhenium(Re—Re)]
Central atom: 
Rhenium
Compound type: 
Oligomer
Valence Number (VN): 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN): 
CN: 7
Electron Number (EN): 
EN: 18
CLOVEBXZ: 
Re«V3C7OIIE18B7Z0X3L4»
MLXZQ± class: 
[MX3L4]
MLXZ class: 
MX3L4
Attached groups: 
SiPh₂ (diphenylsilylene)
CO (carbonyl)

[Re(OBuᵗ)₂(CO)(≡CBuᵗ)]₂

Formula Unicode styled: 
[Re(OBuᵗ)₂(CO)(≡CBuᵗ)]₂
Compound name(s): 
bis-[(μ₂-Neopentylidyne)-bis(t-butoxy)-carbonyl-rhenium(Re=Re)]
Central atom: 
Rhenium
Compound type: 
Oligomer
Valence Number (VN): 
VN: 7
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 16
CLOVEBXZ: 
Re«V7C6OVE16B8Z0X7L1»
MLXZQ± class: 
[MX7L1]
MLXZ class: 
MX7L1
Attached groups: 
OBuᵗ (t-butyloxy)
CO (carbonyl)
≡CBuᵗ (neopentylidyne)

[Re(OBuᵗ)₂(≡CBuᵗ)]₂

Formula Unicode styled: 
[Re(OBuᵗ)₂(≡CBuᵗ)]₂
Compound name(s): 
bis-[(Neopentylidyne-bis(t-butoxy)-rhenium(Re=Re)]
Central atom: 
Rhenium
Compound type: 
Oligomer
Valence Number (VN): 
VN: 7
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN): 
CN: 4
Electron Number (EN): 
EN: 14
CLOVEBXZ: 
Re«V7C4OVE14B7Z0L0X7»
MLXZQ± class: 
[MX7]
MLXZ class: 
MX7
Attached groups: 
OBuᵗ (t-butyloxy)
≡CBuᵗ (neopentylidyne)

[Re(O)(μ₂–O)(Cp*)]₂

Formula Unicode styled: 
[Re(O)(μ₂–O)(Cp*)]₂
Compound name(s): 
bis-[(μ₂-oxo)-oxo-(η⁵-pentamethyl-cyclopentadienyl)-rhenium]
Central atom: 
Rhenium
Compound type: 
Oligomer
Valence Number (VN): 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 18
CLOVEBXZ: 
Re«V5C6OVE18B8Z0X5L3»
MLXZQ± class: 
[MX5L3]
MLXZ class: 
MX5L3
Attached groups: 
O (oxo ⭀O X₂L)
O (μ₂–oxo X+X)
Cp* (η⁵-pentamethylcyclopentadienyl)

[Re(O)(μ₂-Se)(Cp*)]₂

Formula Unicode styled: 
[Re(O)(μ₂-Se)(Cp*)]₂
Compound name(s): 
bis-[(μ₂-seleno)-oxo-(η⁵-pentamethyl-cyclopentadienyl)-rhenium]
Central atom: 
Rhenium
Compound type: 
Oligomer
Valence Number (VN): 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN): 
CN: 6
Electron Number (EN): 
EN: 18
CLOVEBXZ: 
Re«V5C6OVE18B8Z0X5L3»
MLXZQ± class: 
[MX5L3]
MLXZ class: 
MX5L3
Attached groups: 
O (oxo ⭀O X₂L)
Se (μ₂-seleno X–X)
Cp* (η⁵-pentamethylcyclopentadienyl)

[Re(O)(MeC≡CMe)₂]₂

Formula Unicode styled: 
[Re(O)(MeC≡CMe)₂]₂
Compound name(s): 
bis-[(bis(η²-Dimethylacetylene)-oxo-rhenium(Re—Re)]
Central atom: 
Rhenium
Compound type: 
Oligomer
Valence Number (VN): 
VN: 3
Oxidation Number (ON) (Roman numerals): 
ON: (II)
Coordination Number (CN): 
CN: 4
Electron Number (EN): 
EN: 18
CLOVEBXZ: 
Re«V3C4OIIE18B7Z0X3L4»
MLXZQ± class: 
[MX3L4]
MLXZ class: 
MX3L4
Attached groups: 
O (oxo X₂)
MeC≡CMe (butyne L₂)

[Re(Mes)(⭀NBuᵗ)(μ₃–O)]₂

Formula Unicode styled: 
[Re(Mes)(⭀NBuᵗ)(μ₃–O)]₂
Compound name(s): 
bis-[(t-Butylimido-N)-(μ₂-oxo)-mesityl-rhenium]
Central atom: 
Rhenium
Compound type: 
Oligomer
Valence Number (VN): 
VN: 5
Oxidation Number (ON) (Roman numerals): 
ON: (V)
Coordination Number (CN): 
CN: 5
Electron Number (EN): 
EN: 16
CLOVEBXZ: 
Re«V5C5OVE16B7Z0X5L2»
MLXZQ± class: 
[MX5L2]
MLXZ class: 
MX5L2
Attached groups: 
Mes (mesityl)
⭀NBuᵗ (⭀N t-butylimino)
O (μ₃–oxo X₂L)